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Pulsed Gamma Neutron Activation Analysis System for the Assay of RCRA Metals

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TTP#: FT0-6-IP01; Tech ID#: 2226
Project Overview

The objective of this project is to develop and demonstrate a field-deployable pulsed gamma neutron activation analysis (PGNAA) system capable of assaying the RCRA metal contents of 55-gallon drums of mixed waste. Westinghouse Science and Technology Center was originally awarded a FETC Contract on 9/30/93 to perform a treatability study using Prompt Gamma Neutron Activation Analysis (PGNAA). The project objective was to develop, fabricate and demonstrate an in situ analysis method for determining the level of radioactive and hazardous contaminants in concrete floors (with discrimination at higher regulatory levels) at selected DOE sites. This project ended on 4/30/95. The contractor further developed this analysis system for the more stringent requirements of determining RCRA hazardous metals at lower detection levels when their system was selected and successfully tested under a DOE Idaho Operations Contract. Under this INEL contract, a performance test was carried out during FY 1996 with funding from the DOE Mixed Waste Focus Area (MWFA) to determine the non-invasive elemental assay capabilities of commercial companies for RCRA metals present in 8-gallon drums containing surrogate waste. Commercial companies were required to be experienced in the use of PGNAA techniques and to have a prototype assay system with which to conduct the test assays. Potential participants were identified through responses to a call for proposals advertised in the Commerce Business Daily and through personal contacts. Six companies were originally identified. Two of these six were willing and able to participate in the performance test, with some subsidizing from the DOE MWFA. Of these two companies, the Westinghouse Science and Technology Center scored the highest on the performance test and successfully identified the presence of RCRA elements cadmium, mercury and lead in all of the blind samples.

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