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Vadose Zone Monitoring System

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TTP#: SR0-9-SS31; Tech ID: 647

Project Overview
The Vadose Zone Monitoring System provides unattended, automated monitoring of multiple vapor sampling locations for unsaturated zone measurements. The vadose zone is the unsaturated area between the ground surface and the water table. Deep vadose zone refers to sites where the water table is generally deeper than 100 feet. Movement of vapor or volatile contaminants in the vadose zone is by diffusion or advection. Movement by diffusion is a result of a concentration gradient, while advective movement forces vapor or volatile contaminants through the vadose zone by some means, such as changes in barometric pressure with time. By utilizing the Vadose Zone Monitoring System the predominant mechanism of vapor or volatile contaminant movement can be made and, hence, provide more accurate predictions of the rate of movement of the contaminants to the water table.

Technology Description
The Vadose Zone Monitoring System integrates pressure sensors and gas sampling devices in a stand alone field system that performs real time measurement at up to 45 sampling ports in single or multiple wells. The wells can range from test holes of one to two inches in diameter to boreholes eight inches in diameter. SEAMIST[TM] membranes are the principal method of injection and sampling port emplacement. The sampling system utilizes a Bruel and Kjaer gas analyzer, a barometric pressure sensor, a differential pressure sensor, and a solenoid valve system to sequentially connect each sampling port to a sensor. Also, temperature sensors and thermocouple psychrometers which measure soil water potential are located in selected wells. The system being tested at Sandia's Mixed Waste Landfill (MWL) monitors trichloroethylene (TCE), carbon dioxide (CO2 ), and sulfur hexafluoride (SF6 ). To perform a gas movement experiment, 250 parts per million sulfur hexafluoride (0.025%) is injected into the ground through a sampling port and the monitoring system is started. Pressure data from 45 ports are collected/stored once every three hours and gas analysis data from 45 ports are collected/stored every six hours. The system runs automatically without supervision. Data are periodically downloaded using a standard portable personal computer and analyzed using standard spreadsheet programs. The pressure data are correlated to gas analysis data from each well to determine the effects of changes in barometric pressure due to a change in weather on the movement of the vapor through the soil. The movement of the vapor is analogous to the movement of TCE, the contaminant of interest, in the soil.

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