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Pd2.28(1)Zn10.37(1)Al0.35(1), a ternary gamma-brass-type structure

TitlePd2.28(1)Zn10.37(1)Al0.35(1), a ternary gamma-brass-type structure
Publication TypeJournal Article
Year of Publication2010
AuthorsThimmaiah S, Miller GJ
Journal TitleActa Crystallographica Section E-Structure Reports Online
Volume66
PagesI5-U129
Date Published02/01
ISBN Number1600-5368
Accession NumberISI:000274115200003
Keywordsphase
Abstract

Palladium zinc aluminium (2.28/10.37/0.35), Pd2.28(1)Zn10.37(1)-Al-0.35(1), represents the upper limit of Al substitution into the parent cubic gamma-brass Pd2+xZn11-x. The structure can be described in terms of a 26-atom cluster consisting of an inner tetrahedron (IT), an outer tetrahedron (OT), an octahedron (OH) and a cuboctahedron (CO), with the substituted Al atoms partially occupying the IT (.3m) and CO (..m) sites.
URL<Go to ISI>://000274115200003
DOIDoi 10.1107/S1600536810000723