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Switching slow relaxation in a (Mn3MnIV)-Mn-III cluster: an example of grafting single-molecule magnets onto polyoxometalates

TitleSwitching slow relaxation in a (Mn3MnIV)-Mn-III cluster: an example of grafting single-molecule magnets onto polyoxometalates
Publication TypeJournal Article
Year of Publication2010
AuthorsFang XK, Speldrich M, Schilder H, Cao R, O'Halloran KP, Hill CL, Kogerler P
Journal TitleChemical Communications
Volume46
Pages2760-2765
ISBN Number1359-7345
Accession NumberISI:000276376000013
KeywordsATOMIC-FORCE MICROSCOPY, conducting polymer, conjugated polymers, films, friction, LITHOGRAPHY, monolayers, nanolithography, polyaniline nanofibers, SENSOR
Abstract

Binding an established single-molecule magnet cluster of distorted cubane type [(Mn3MnO4)-Mn-III-O-IV] to the lacunary site of an {alpha-P2W15} polyoxotungstate scaffold results in a surprising zero-field splitting inversion and the subsequent loss of magnetization bistability.
URL<Go to ISI>://000276376000013