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{Mn14W48} aggregate: the perspective of isopolyanions as ligands

Title{Mn14W48} aggregate: the perspective of isopolyanions as ligands
Publication TypeJournal Article
Year of Publication2011
AuthorsFang XK, Luban M
Journal TitleChemical Communications
Volume47
Pages3066-3068
Date Published03/21
Type of ArticleArticle
ISBN Number1359-7345
Accession NumberISI:000287865100007
Keywordsanion, cluster, manganese carboxylate, POLYOXOMETALATE
Abstract

The assembly of a tetradeca-manganese magnetic cluster [Mn14W48O192H20](26-), containing two high spin Mn-7 cores and supported exclusively by isopolytungstate ligands, demonstrates the promising perspective of using "defect'' isopolyanions as ligands/synthons to construct large aggregated structures and model the surface deposition of molecular magnets.
URL<Go to ISI>://000287865100007http://pubs.rsc.org/en/content/articlepdf/2011/cc/c0cc04403b
DOI10.1039/c0cc04403b
Alternate JournalChem. Commun.