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A polyoxometalate-based single-molecule magnet with an S=21/2 ground state

TitleA polyoxometalate-based single-molecule magnet with an S=21/2 ground state
Publication TypeJournal Article
Year of Publication2012
AuthorsFang XK, Kogerler P, Speldrich M, Schilder H, Luban M
Journal TitleChemical Communications
Volume48
Pages1218-1220
Date Published01/30
Type of ArticleArticle
ISBN Number1359-7345
Accession NumberWOS:000298943600003
Keywordsbistability, cluster, complexes, ion, manganese carboxylate
Abstract

Ligand modification transforms a polyoxometalate-anchored cubane-type [Mn(3)(III)Mn(IV)O(4)] core into a centrosymmetric [Mn(6)(III)Mn(IV)O(8)] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn(4)O(4)] cubane-based single-molecule magnets.
URL<Go to ISI>://WOS:000298943600003
DOI10.1039/c1cc15520b
Alternate JournalChem. Commun.