A Homochiral 2D Copper(II) Coordination Framework
| Title | A Homochiral 2D Copper(II) Coordination Framework |
| Publication Type | Journal Article |
| Year of Publication | 2009 |
| Authors | Fielden J, Quasdorf K, Ellern A, Kogerler P |
| Journal Title | European Journal of Inorganic Chemistry |
| Pages | 717-720 |
| Date Published | 02/01 |
| ISBN Number | 1434-1948 |
| Accession Number | ISI:000264045800002 |
| Keywords | chiral molecule, chirality, complexes, coordination modes, dichroism, ferrimagnet, ligand design, magnetic properties, magnetic-properties, n, o ligands, t-c |
| Abstract | Reaction of copper(II) salts with (S)-phenylethylaminodiacetate [(S)-peadaa] results in the 2D coordination network (S)-[Cu(peadaa)](n) (space group P2(1)), which displays an unusual Cu center dot center dot center dot Cu connectivity mode. Solid-state circular dichroism. (CD) indicates a strong interaction between the ligand chiral centre and the metal centres, whereas magnetic measurements show both antiferromagnetic coupling and strong ligand field effects. ((C) Wiley-VCH Verldg GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) |
| URL | <Go to ISI>://000264045800002 |
| DOI | 10.1002/Ejic.200801098 |
